The effect of Neutralized Phosphogypsum on the Content of Stable Strontium in Slightly Saline Chernozem and Winter Wheat Grain in the Conditions of the Central Ciscaucasia

Authors

DOI:

https://doi.org/10.31279/2949-4796-2025-15-3-78-87

Keywords:

neutralized phosphogypsum, phosphogypsum doses, common chernozem, winter wheat, brackish soils, chemical reclamation, stable strontium
272 446

Abstract

Introduction. The use of neutralized phosphogypsum as a chemical ameliorant is an effective method for enhancing agricultural productivity on solonetz soils in the central Ciscaucasia region. However, given that the ameliorant contains strontium in its composition, confirmation of its environmental safety is required.
Aim. To determine the residual effect of neutralized phosphogypsum application on the content of stable strontium in slightly solonetzic common chernozem and winter wheat grain under the conditions of the central Ciscaucasia.
Materials and methods. The study was conducted from 2021 to 2024 in a production-scale experiment located in the zone of unstable moisture availability in the Stavropol Krai of Russia, within the Andropovsky municipal district. The effect of different application rates of neutralized phosphogypsum (5, 10, 15, and 20 t/ha) was investigated. The soil of the experimental site was slightly solonetzic common chernozem. Soil samples were collected from the plow layer (0-20 cm) and sub-plow layer (20-40 cm).
Results. The application of neutralized phosphogypsum rates did not result in a statistically significant increase in the stable strontium content in the soil. The average content over the three years of study across the experimental treatments varied within the range of 109-132 mg/kg. A significant increase in stable strontium was detected in winter wheat grain in treatments with the application of 10-20 t/ha of the ameliorant, ranging from 0.44 to 0.68 mg/kg. However, the resulting calcium-to-strontium ratio confirmed the safety of the produced grain.
Conclusions. The application of neutralized phosphogypsum at rates ranging from 5 to 20 t/ha on slightly solonetzic common chernozem does not lead to contamination of the soil or winter wheat grain with stable strontium.

References

Babenko A.A., Babichev A.N. Impact of Chemical Ameliorant Doses on the Degree

of Salinity and Soil Absorption Complex Composition. Ways of Increasing the Efficiency of Irrigated Agriculture. 2025;1(95):265-281. (In Russ.)

Nekrasov R.V., Sheudzhen A.Kh., Baibekov R.F. et al. Agroeconomic and Ecological Aspects of Chemical Reclamation of Saline Soils. Agriculture. 2021;8:3-7. (In Russ.)

Soumya N., Mishra C.S.K., Guru B.C., Rath M. Effect of phosphogypsum amendment on soil physico-chemical properties, microbial load and enzyme activities. Journal of Environmental Biology. 2011;32(5):613-617.

Maina L.W., Kiegiel K., Zakrzewska G. Challenges and Strategies for the Sustainable Environmental Management of Phosphogypsum. Sustainability. 2025;17.3473. https://doi.org/10.3390/su17083473

Qi J., Zhu H., Zhou P., Wang X. Application of Phosphogypsum in Soilization: a Review. International Journal of Environmental Science and Technology. 2023;20(9) https://doi.org/10.1007/s13762-023-04783-2

Mu L., Zhou H., Li. A., Wang. L. The Effects of the Combined Application of Biochar and Phosphogypsum on the Physicochemical Properties of Cd-Contaminated Soil and the Yield Quality of Chinese Cabbage. Agriculture. 2024;14(11):1865. https://doi.org/10.3390/agriculture14111865

Tsyganova A.A., Khripovich A.A., Zelenukho E.V., Skuratovich I.V. Use of Phosphogypsum in the Reclamation of Saline Lands. Bulletin of the Brest State Technical University. 2025;1(136):165-170. (In Russ.) https://doi.org/10.36773/1818-1112-2025-136-1-165-170

Maina L.W., Kiegiel K., Chajduk E., Zakrzewska G. Chemical and Radiochemical Characterization of Phosphogypsum from Poland. Nukleonika. 2024;69(2):113-117. https://doi.org/10.2478/nuka-2024-0016

Jin Y., Yang D., Wu Y., Zhou F. Preparation of Biofertilizer with Phosphogypsum and Straw: Microbial Community Changes and Plant Growth Effects. Journal of Soil Science and Plant Nutrition. 2024;24(4) https://doi.org/10.1007/s42729-024-01806-w

Kulikova E.V., Gorbunova N.S., Kulikov Yu.A. Effect of Reclamation with Phosphogypsum on the Ecological Status of Chernozem Soils of the Kamennaya Steppe. Bulletin of the Voronezh State Agrarian University. 2023;2(77):81-89. (In Russ.)

Lyubimova I.N., Borisochkina T.I. Influence of Potentially Dangerous Chemical Elements Contained in Phosphogypsum on the Environment. Russian Academy of Agricultural Sciences, State Scientific Institution Soil Institute Named After V. V. Dokuchaev. Moscow: GNU Soil Institute Named After V.V. Dokuchaev, RASN. 2007.46. (In Russ.)

Grechishkina Yu.I., Matvienko A.V. The Effect of Neutralized Phosphogypsum on the Stable Strontium Content in Soil and Grain of Winter Wheat on Slightly Saline Chernozem in the Conditions of the Central Ciscaucasia. Fundamental and Applied Scientific Research: Innovation in the Modern World: A Collection of Scientific Articles Based on the Materials of the X International Scientific and Practical Conference in 3 Parts. Ufa, March 21, 2023. Volume Part 1. Ufa: Limited Liability Company Scientific Publishing Center "Bulletin of Science". 2023;157-161. (In Russ.)

Belyuchenko I.S. Features of Mineral Waste and the Expediency of their Use in the Formation of Complex Composts. Polythematic Online Scientific Journal of Kuban State Agrarian University. 2014;101:875–895.

Gmoshinsky I.V., Khotimchenko S.A. Stable Strontium in the Environment and Food Products: Toxicity, Assessment of Exposure and Potential Risks. Health Risk Analysis - 2024: Proceedings of the XIV All-Russian Scientific and Practical Conference with International Participation. In 2 volumes, Perm, May 15-16, 2024. Perm: Federal Scientific Center for Medical and Preventive Technologies for Public Health Risk Management. 2024;292-301. (In Russ.)

Vizirskaya, M.M., Akanova, N.I., Beltyukov, L.P. Efficiency of Phosphogypsum Application During Cultivation of Oil Flax and Winter Wheat. Plodorodie. 2020;5(116):66–68. (In Russ.) https://doi.org/10.25680/S19948603.2020.116.19

Akanova N.I. Neutralized Phosphogypsum is a Promising Agrochemical Means of Agricultural Intensification. Plodorodie. 2013;1(70):2-7. (In Russ.)

Agapova P.V., Kiselev M.V., Freidkin I.A. Assessment of Biological Efficiency of Application of Defluorinated Phosphogypsum as Residual Fertilizer. Proceedings of the St. Petersburg State Agrarian University. 2024;1(75):48-57. (In Russ.) https://doi.org/10.24411/2078-1318-2023-5-72-80

Baibekov R.F., Shilnikov I.A., Akanova N.I. et al. Scientific and Practical Recommendations on the Use of Neutralized Phosphogypsum as a Chemical Meliorant and Sulfur Fertilizer. Ministry of Agriculture of the Russian Federation, Russian Academy of Agricultural Sciences, All-Russian Scientific Research. D. N. Pryanishnikov Institute of Agrochemistry. Moscow: All-Russian Scientific Research. D. N. Pryanishnikov Institute of Agrochemistry. 2012.56. (In Russ.)

Luo A., Li J., Xiao Y., He Z. Engineering Soil Quality and Water Productivity Through Optimal Phosphogypsum Application Rates. Agronomy. 2024;15(1):35 https://doi.org/10.3390/agronomy15010035

Kuznetsov A.V. et al. Guidelines for the Determination of Heavy Metals in Farmland Soils and Crop Production. Center. agrochem Institute. rural household services. 2nd ed., revised and add. Mosco : TsINAO, 1992.61. (In Russ.)

Grechishkina Y.I., Matvienko A.V. The Efficiency of Winter Wheat Production on Slightly Saline Common Chernozem Using Phosphogypsum Neutralized in the Conditions of the Central Ciscaucasia. Agrarian Bulletin of the North Caucasus. 2025;15(2):63-73. (In Russ.) https://doi.org/10.31279/2949-4796-2025-15-2-63-73 EDN VQYVVA

Dospekhov B.A. Methodology of Field Experience (With the Basics of Statistical Processing of Research Results). 6th ed., erased. Moscow: Alliance. 2011.351. (In Russ.)

Yagodin B.A., Zhukov Yu.P., Kobzarenko V.I. Agrochemistry: Textbook for Universities. 4th ed. St. Petersburg: Lan. 2023.584. (In Russ.)

How to Cite

Grechishkina Ю. И., & Matvienko А. (2025). The effect of Neutralized Phosphogypsum on the Content of Stable Strontium in Slightly Saline Chernozem and Winter Wheat Grain in the Conditions of the Central Ciscaucasia. Agrarian Bulletin of the North Caucasus, 15(3), 78–87. https://doi.org/10.31279/2949-4796-2025-15-3-78-87

Issue

Section

Agrochemistry, Agro-Soil Science, Plant Protection